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The newest dz2 and you will dx2-y2 orbitals lack as the head get in touch with because the ligands form of fit earlier or slip by this type of orbitals, hence reducing the electron-electron repulsion plus the energy of your own orbital. The newest oxidation condition of one’s metal as well as establishes exactly how short otherwise highest Δ try. The better the new oxidization condition of one’s steel, the brand new more powerful the new ligand career that’s authored. In the event the there have been two precious metals with the exact same d electron setup, the one to your high oxidization state is far more likely to be reduced twist versus one to your lower oxidization county.

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